Luxurious Specimens

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Carbonado: the black diamond that may have come from the stars

Education only. Carbonado’s origin is unresolved and debated. Nothing on these pages describes, or is connected to, any Luxurious Specimens lot. No lot is claimed to be carbonado or to come from space.

Supernova 1987A, imaged by Hubble, shown for illustration. It is not the source of carbonado.
Supernova 1987A, imaged by Hubble, shown for illustration. It is not the source of carbonado. Credit: NASA, ESA, and R. Kirshner (Harvard-Smithsonian Center for Astrophysics and Gordon and Betty Moore Foundation) and P. Challis (Harvard-Smithsonian Center for Astrophysics). Source (CC BY 4.0).

Carbonado is a black, porous diamond made of countless tiny crystals bonded together. Portuguese prospectors in Brazil named it for its resemblance to charcoal[1,2]. It is found only in Brazil and the Central African Republic[1].

In 2006, Jozsef Garai, Stephen Haggerty and colleagues published infrared spectra of carbonado measured with synchrotron light at Brookhaven National Laboratory. They reported hydrogen and single-nitrogen signatures and compared the spectra with lab-grown and presolar diamonds, concluding that carbonado formed in a hydrogen-rich interstellar environment[3,4]. The NSF release described the idea that carbonado formed in exploding stars and arrived in bodies a kilometer or more across[1].

This is a hypothesis, not settled science. Other teams found that some infrared bands come from water and carbonate inside the diamond and proposed growth from fluids on Earth[5,6]. Earth-based ideas also include meteorite impact into crustal rocks[7], subduction, and radiation from uranium-rich carbon[8]. A GIA review weighs these competing ideas[2], while a fuller critique is in Haggerty’s 2014 review[9].

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Sources

  1. U.S. National Science Foundation news release (Jan. 9, 2007), “Diamonds from outer space: geologists discover origin of Earth's mysterious black diamonds,” via EurekAlert! https://www.eurekalert.org/news-releases/910688
  2. Gems & Gemology (GIA), Summer 2017, “Carbonado Diamond: A Review of Properties and Origin.” https://www.gia.edu/gems-gemology/summer-2017-carbonado-diamond
  3. Garai, J., Haggerty, S. E., Rekhi, S. & Chance, M. (2006). Infrared absorption investigations confirm the extraterrestrial origin of carbonado diamonds. The Astrophysical Journal Letters 653, L153–L156. https://doi.org/10.1086/510451
  4. Brookhaven National Laboratory Newsroom (Jan. 10, 2007), “Diamonds from Outer Space.” https://www.bnl.gov/newsroom/news.php?a=110576
  5. Ishibashi, H. et al. (2012). Hydrous fluid as the growth media of natural polycrystalline diamond, carbonado. American Mineralogist. https://doi.org/10.2138/am.2012.4097
  6. “Infrared and Raman spectroscopic observations of Central African carbonado and implications for its origin” (2008). European Journal of Mineralogy. https://doi.org/10.1127/0935-1221/2008/0020-1817
  7. Smith, J. V. & Dawson, J. B. (1985). Carbonado: Diamond aggregates from early impacts of crystal rocks? Geology 13(5), 342. https://doi.org/10.1130/0091-7613(1985)13%3C342:CDAFEI%3E2.0.CO;2
  8. Daulton, T. L. & Ozima, M. (1996). Radiation-induced diamond formation in uranium-rich carbonaceous materials. Science 271, 1260–1263. https://doi.org/10.1126/science.271.5253.1260
  9. Haggerty, S. E. (2014). Carbonado: Physical and chemical properties, a critical evaluation of proposed origins, and a revised genetic model. Earth-Science Reviews. https://doi.org/10.1016/j.earscirev.2013.12.008

Image credits

ESA/Hubble and ESA/Webb images are used under CC BY 4.0. Use of these images does not imply endorsement by ESA, NASA, CSA or STScI. NASA images are public domain and credited as requested.